Improving alkynyl(aryl)iodonium salts: 2-anisyl as a superior aryl group

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Improving alkynyl(aryl)iodonium salts: 2-anisyl as a superior aryl group.

The majority of alkynyl(aryl)iodonium salts reported in the literature are derived from iodobenzene. This article describes the effects of varying this iodoarene building block on the synthesis, reactivity and stability of these salts. Two procedures to synthesize a variety of known and novel alkynyl(aryl)iodonium tosylates directly from the iodoarene are reported. In the reactions of these sal...

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ژورنال

عنوان ژورنال: Org. Biomol. Chem.

سال: 2014

ISSN: 1477-0520,1477-0539

DOI: 10.1039/c4ob00556b